Etymology

dust off a batter

Today it means: for a pitcher to throw a pitch at or near the batter, typically to frighten the batter or to have him stand farther away from home plate. Full definition →

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The story

From the concept that a pitch thrown very close to a batter will remove some dust or dirt from the batter's uniform either by brushing against it or causing a breeze very close to it, or alternatively by the batter jumping away from the pitch to avoid being hit.

Etymology from Wiktionary, CC BY-SA 4.0.