Etymology

painstaking

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Today it means: Carefully attentive to details; studious; diligent in performing a process or procedure. Full definition →

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The story

From pains + taking; see take pains. The /ˈpeɪnˌsteɪkɪŋ/ pronunciation which dominates in the United States suggests a reanalysis of the word as pain + staking.

Etymology from Wiktionary, CC BY-SA 4.0.